Nuclear magnetic resonance spectroscopy. A stereospecific ^3J_(CF) coupling in the low-temperature ^(13)C nmr spectrum of 1,1-difluorocyclohexane

The proton-decoupled ^(13)C nmr spectrum of 1,1-difluorocyclohexane has been examined at room temperature and at -90 degrees C. There are only minor changes in the one-bond and two-bond carbon-fluorine scalar coupling constants at the lower temperature; however, the triplet observed for C-3 (^3J_(CF) = 4.7 Hz) collapses to a doublet (3JCF = 9.5 Hz) at -90 °C. It is proposed that only the equatorial fluorine is coupled with the C-3 carbon as the result of operation of a back-lobe orbital interaction

Conditions for the confirmation of three-particle non-locality

The notion of genuine three-particle non-locality introduced by Svetlichny \cite{Svetlichny} is discussed. Svetlichny's inequality which can distinguish between genuine three-particle non-locality and two-particle non-locality is analyzed by reinterpreting it as a frustrated network of correlations. Its quantum mechanical maximum violation is derived and a situation is presented that produces the maximum violation. It is shown that the measurements performed in recent experiments to demonstrate GHZ entanglement \cite{Bouwmeester}, \cite{Pan} do not allow this inequality to be violated, and hence can not be taken as confirmation of genuine three-particle non-locality. Modifications to the experiments that would make such a confirmation possible are discussed.Comment: minor revisions, references adde

Flavor SU(4) breaking between effective couplings

Using a framework in which all elements are constrained by Dyson-Schwinger equation studies in QCD, and therefore incorporates a consistent, direct and simultaneous description of light- and heavy-quarks and the states they constitute, we analyze the accuracy of SU(4)-flavor symmetry relations between {\pi}{\rho}{\pi}, K{\rho}K and D{\rho}D couplings. Such relations are widely used in phenomenological analyses of the interactions between matter and charmed mesons. We find that whilst SU(3)-flavor symmetry is accurate to 20%, SU(4) relations underestimate the D{\rho}D coupling by a factor of five.Comment: 5 pages, two figure

Constructing a gazebo: supporting teamwork in a tightly coupled, distributed task in virtual reality

Many tasks require teamwork. Team members may work concurrently, but there must be some occasions of coming together. Collaborative virtual environments (CVEs) allow distributed teams to come together across distance to share a task. Studies of CVE systems have tended to focus on the sense of presence or copresence with other people. They have avoided studying close interaction between us-ers, such as the shared manipulation of objects, because CVEs suffer from inherent network delays and often have cumbersome user interfaces. Little is known about the ef-fectiveness of collaboration in tasks requiring various forms of object sharing and, in particular, the concurrent manipu-lation of objects. This paper investigates the effectiveness of supporting teamwork among a geographically distributed group in a task that requires the shared manipulation of objects. To complete the task, users must share objects through con-current manipulation of both the same and distinct at-tributes. The effectiveness of teamwork is measured in terms of time taken to achieve each step, as well as the impression of users. The effect of interface is examined by comparing various combinations of walk-in cubic immersive projection technology (IPT) displays and desktop devices

Quantum-mechanical calculations of the stabilities of fluxional isomers of C_4H_7^+ in solution

Although numerous quantum calculations have been made over the years of the stabilities of the fluxional isomers of C4H7+, none have been reported for other than the gas phase (which is unrealistic for these ionic species) that exhibit exceptional fluxional properties in solution. To be sure, quantum-mechanical calculations for solutions are subject to substantial uncertainties, but nonetheless it is important to see whether the trends seen for the gas-phase C4H7+ species are also found in calculations for polar solutions. Of the C4H7+ species, commonly designated bisected-cyclopropylcarbinyl 1, unsym-bicyclobutonium-2, sym-bicyclobutonium 3, allylcarbinyl 4, and pyramidal structure 6, the most advanced gas-phase calculations available thus far suggest that the order of stability is 1 ≥ 2 ≥ 3 >> 4 >> 6 with barriers of only ~1 kcal/mol for interconversions among 1, 2, and 3. We report here that, when account is taken of solvation, 2 turns out to be slightly more stable than 1 or 3 in polar solvents. The pattern of the overall results is unexpected, in that despite substantial differences in structures and charge distributions between the primary players in the C4H7+ equilibria and the large differences in solvation energies calculated for the solvents considered, the differential solvent effects from species to species are rather small

Deconfinement and Hadron Properties at Extremes of Temperature and Density

After introducing essential, qualitative concepts and results, we discuss the application of Dyson-Schwinger equations to QCD at finite T and mu. We summarise the calculation of the critical exponents of two-light-flavour QCD using the chiral and thermal susceptibilities; and an algebraic model that elucidates the origin of an anticorrelation between the mu- and T-dependence of a range of meson properties. That model also provides an algebraic understanding of why the finite-T behaviour of bulk thermodynamic properties is mirrored in their mu-dependence, and why meson masses decrease with mu even though f_pi and - increase. The possibility of diquark condensation is canvassed. Its realisation is uncertain because it is contingent upon an assumption about the quark-quark scattering kernel that is demonstrably false in some applications; e.g., it predicts the existence of coloured diquarks in the strong interaction spectrum, which are not observed.Comment: Summary of presentations at the Workshop on QCD at Finite Baryon Density, Bielefeld, Germany, 27-30/April/1998, 13 pages, 9 figures, espcrc1.sty, epsfig.sty. Correcting typsetting problem

Probing Extreme-Density Matter with Gravitational Wave Observations of Binary Neutron Star Merger Remnants

We present a proof-of-concept study, based on numerical-relativity simulations, of how gravitational waves (GWs) from neutron star merger remnants can probe the nature of matter at extreme densities. Phase transitions and extra degrees of freedom can emerge at densities beyond those reached during the inspiral, and typically result in a softening of the equation of state (EOS). We show that such physical effects change the qualitative dynamics of the remnant evolution, but they are not identifiable as a signature in the GW frequency, with the exception of possible black-hole formation effects. The EOS softening is, instead, encoded in the GW luminosity and phase and is in principle detectable up to distances of the order of several Mpcs with advanced detectors and up to hundreds of Mpcs with third generation detectors. Probing extreme-density matter will require going beyond the current paradigm and developing a more holistic strategy for modeling and analyzing postmerger GW signals.Comment: 5 pages, 3 figures. Matches version accepted on ApJ